I'm old so that will be reflected in my choices.
I am also sticking to the thread title TV CHARACTERS

A big YES to Wilma Deering from Buck Rogers

I also had a crush on 99 from Get Smart and Sam from Bewitched

I am embarrassed to admit that I could not take my eyes off of Gloria from All in the Family but I couldn't stand her voice

Finally forget Catwoman - Batgirl did it for me in the Adam West Batman series.